Russian Federation
Russian Federation
Russian Federation
UDC 551.4
Purpose. The study is purposed at identifying the characteristic features of content of dissolved forms of macrocompounds and nutrients in the river estuarine areas of Bolshoi Sochi (Sochi, Matsesta, Khos-ta, Kudepsta and Mzymta). Methods and Results. The surface water samples were taken in the river estuaries of Sochi, Matsesta, Khosta, Kudepsta and Mzymta rivers in early November during the autumn-winter flood season. The concentrations of nutrient compounds were determined by the spectrophotometric methods and those of macrocompounds – by the capillary electrophoresis one. Distribution of water hydrochemical character-istics corresponds to the classical pattern typical of the river-sea system. Chemical composition of water in the rivers is of the hydrocarbonate-calcium type, except for the Matsesta River where the composition is mixed. The highest concentrations of nitrogen compounds were revealed in the rivers Matsesta and Kudepsta, and those of phosphates – in the Sochi River. The Kudepsta River water is characterized by the abnormally high values of total alkalinity. As for the domestic water use, the measurements of nutri-ent compounds have shown no excess of their maximum permissible concentrations. Conclusions. Water chemical composition in the river mouths under study is conditioned by the impact of natural and anthropogenic factors. For the Matsesta River, the key natural factor is the discharge of mineral groundwater, whereas the anthropogenic factor is the wastewater discharge. The combination of these factors and the mouth overlap resulted in the development of eutrophication processes. For the Kudepsta River, the high background alkalinity value is of natural origin, but the increased concentra-tions of nutrients (nitrogen and phosphorus) are associated with intensive construction activities in the mouth area.
mouth area, Black Sea, Bolshoi Sochi, anthroogenic impact, chemical composition of water, nutrients, hydrochemical composition, macrocomponents
1. Gordeev V. V. Geohimiya sistemy reka-more. Moskva : IP Matushkina I.I., 2012. 452 s.
2. Makkaveev P. N., Zav'yalov P. O. Stok malyh i srednih rek rossiyskogo poberezh'ya Cher-nogo morya i ego vliyanie na harakteristiki vod // Sistema Chernogo Morya. Moskva : Nauchnyy mir, 2018. S. 287–321. EDN THXBYZ. https://doi.org/10.29006/978-5-91522-473-4.2018.287-322
3. Mihaylov V. N. Gidrologiya ust'ev rek. Moskva : Izd-vo MGU, 1998. 176 s.
4. Effects of salinity on nitrogen reduction pathways in estuarine wetland sediments / H. Zheng [et al.] // Marine Pollution Bulletin. 2024. Vol 207. 116834. https://doi.org/10.1016/j.marpolbul.2024.116834
5. Variability of trace metals in coastal and estuary: Distribution, profile, and drivers / Harmesa [et al.] // Marine Pollution Bulletin. 2022. Vol. 174. 113173. https://doi.org/10.1016/j.marpolbul.2021.113173
6. Tornero V., Hanke G. Chemical contaminants entering the marine environment from sea-based sources: a review with a focus on European seas // Marine Pollution Bulletin. 2016. Vol. 112, iss. 1–2. P. 17–38. https://doi.org/10.1016/j.marpolbul.2016.06.091
7. Spatial, temporal, and vertical variability of nutrients in the Southeastern Black Sea / A. Alkan [et al.] // Chemosphere. 2022. Vol. 302. 34809. https://doi.org/10.1016/j.chemosphere.2022.134809
8. Influence of small rivers runoff on the hydrochemical structure of coastal waters of the North-Eastern Black Sea / A. V. Kostyleva [et al.] // Coastal Engineering Practice. 2011. P. 286–297. EDN PELQBR. https://doi.org/10.1061/41190(422)24
9. Pathways and mixing of the North Western river waters in the Black Sea / S. Miladinova [et al.] // Estuarine, Coastal and Shelf Science. 2020. Vol. 236. 106630. https://doi.org/10.1016/j.ecss.2020.106630
10. Gidrofizicheskie i gidrohimicheskie harakteristiki morskih akvatoriy u ust'ev malyh rek rossiyskogo poberezh'ya Chernogo morya / P. O. Zav'yalov [i dr.] // Okeanologiya. 2014. T. 54, № 3. S. 293–308. EDN SEEDFF. https://doi.org/10.7868/S0030157414030150
11. Kostyleva A. V. Raspredelenie rastvorennogo organicheskogo ugleroda v priust'evyh rayonah Bol'shogo Sochi (severo-vostochnaya chast' Chernogo morya) // Okeanologiya. 2015. T. 55, № 2. S. 224–230. EDN TPWLVL. https://doi.org/10.7868/S0030157415020082
12. Makkaveev P. N., Poluhin A. A., Stepanova S. V. Raboty po izucheniyu priust'evyh ob-lastey malyh i srednih rek v pribrezhnoy zone rossiyskogo sektora Chernogo morya // Ekologicheskaya bezopasnost' pribrezhnoy i shel'fovoy zon i kompleksnoe ispol'zovanie resursov shel'fa. 2013. № 27. S. 412–417. EDN VBFSJP.
13. Cavenko A. V. Tipy raspredeleniya rastvorennyh form himicheskih elementov v ust'e-vyh oblastyah rek // Vestnik Moskovskogo universiteta. Seriya 5. Geografiya. 2018. № 2. S. 53–59. EDN YUUDIK.
14. Savenko A. V., Pokrovskiy O. S. Transformaciya makro- i mikroelementnogo sostava stoka rastvorennyh veschestv v ust'yah srednih i malyh rek Chernomorskogo poberezh'ya Rossii // Okeanologiya. 2022. T. 62, № 3. S. 380–402. EDN MJPAOV. https://doi.org/10.31857/S003015742203011X
15. Gordeev V. V., Makkaveev E. P., Kochenkova A. I. Tyazhelye metally v vode i vzvesi v ust'-yah rek i pribrezhnoy zone rossiyskoy chasti Kavkazskogo poberezh'ya Chernogo morya // Vo-da: himiya i ekologiya. 2015. № 11. C. 7–21. EDN WMFKPZ.
16. Ocenka urovnya tehnogennyh zagryazneniy v pribrezhnoy zone Chernogo morya v rayone Ge-lendzhika / V. K. Chasovnikov [i dr.] // Okeanologiya. 2016. T. 56, № 1. S. 76–80. EDN VIOSFX.
17. Litvinenko Yu. S., Zaharihina L. V. Geohimiya i radioekologiya vod i donnyh otlozheniy r. Mzymty chernomorskogo poberezh'ya // Geohimiya. 2022. T. 67, № 4. S. 376–393. https://doi.org/10.31857/S0016752522030049
18. Lesnikova P. S. Izmenenie makroelementnogo sostava rechnyh vod v kontrastnyh geolo-gicheskih usloviyah, reka Sochi Chernomorskogo poberezh'ya Rossii // Vestnik VGU. Seriya: Geografiya. Geoekologiya. 2023. № 3. S. 47–56. EDN GCSFZK. https://doi.org/10.31857/S0016752522030049
19. Dzhaoshvili Sh. Reki Chernogo morya. Tbilisi, 2002. 58 s. (Tehnicheskiy otchet № 71). URL: http://www.eea.europa.eu/ru/publications/technical_report_2002_71/at_ download/file (data obrascheniya: 20.09.2025).
20. Ozseker K., Eruz C., Terzi Y. Spatial distribution and ecological risk evaluation of toxic metals in the southern Black Sea coastal sediments // Marine Pollution Bulletin. 2022. Vol. 182. 114020. https://doi.org/10.1016/j.marpolbul.2022.114020
21. Solorzano L. Determination of ammonia in natural waters by the phenolhypochlorite method // Limnology Oceanography. 1969. Vol. 14, iss. 5. P. 799–801. https://doi.org/10.4319/lo.1969.14.5.0799
22. Shvarcev S. L. Gidrogeohimiya zony gipergeneza. Moskva : Nedra, 1998. 366 s.




